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At the triple point


A) solid, liquid, and gas are all in equilibrium.
B) the vapor pressure of the solid is equal to the vapor pressure of the liquid.
C) the rate of sublimation is equal to the rate of evaporation.
D) a & b
E) all of the above

F) A) and B)
G) D) and E)

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Which do you predict will have the largest intermolecular attraction F2, Cl2, Br2, I2?


A) F2
B) Cl2
C) Br2
D) I2
E) they will all be the same

F) A) and B)
G) D) and E)

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Which do you think will have the highest surface tension?


A) water
B) liquid N2
C) CCl4
D) CHCl3
E) molten NaCl

F) D) and E)
G) B) and C)

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A supercritical fluid has a density that


A) is lower than a liquid.
B) is lower than a gas.
C) is higher than a liquid.
D) is higher than a gas.
E) can be varied from gas-like to liquid-like.

F) B) and E)
G) B) and C)

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Which do you think has a higher boiling point, n-butanol or tert-butanol? Which do you think has a higher boiling point, n-butanol or tert-butanol?   A)  n-butanol because it forms stronger hydrogen bonds. B)  tert-butanol because it forms stronger hydrogen bonds. C)  n-butanol because the linear molecule allows for greater dispersion forces. D)  tert-butanol because the tetrahedral molecule allows for greater dispersion forces. E)  they will be exactly the same.


A) n-butanol because it forms stronger hydrogen bonds.
B) tert-butanol because it forms stronger hydrogen bonds.
C) n-butanol because the linear molecule allows for greater dispersion forces.
D) tert-butanol because the tetrahedral molecule allows for greater dispersion forces.
E) they will be exactly the same.

F) All of the above
G) C) and D)

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The triple point of a compound is at 38.2°C and a pressure of 0.75 atm. A gaseous sample of the substance is held at a constant pressure of 0.79 atm. Initially the sample is at 50°C and is slowly cooled until it is -25°C. What if any phase transitions occur?


A) condensation
B) deposition
C) condensation followed by freezing
D) simultaneous condensation and freezing
E) none of the above

F) A) and C)
G) None of the above

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What types of intermolecular forces would you expect to find in CHCl3?


A) dispersion
B) dipole-dipole
C) hydrogen bonding
D) a & b
E) all of the above

F) C) and D)
G) B) and E)

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Which has the highest vapor pressure at room temperature?


A) methanol
B) ethanol
C) propanol
D) butanol
E) there is no way to predict

F) A) and E)
G) C) and D)

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Generally if a liquid has stronger intermolecular attractions it will have


A) a higher viscosity.
B) a higher vapor pressure.
C) a higher boiling point.
D) a & b
E) b & c
F)  a & c
G)  all of the above

H) A) and F)
I) E) and F)

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At 20°C water has a vapor pressure of 0.0231 atm. If you bubble air through a container of water and collect 1 L of it at a total pressure of 1 atm, how many grams of water are in your sample of air (you can assume it is saturated) ?


A) 9.6×10-4
B) 3.0×10-4
C) 3.0×10-3
D) 1.1×10-2
E) 1.7×10-2

F) All of the above
G) A) and E)

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Dipole-dipole forces are


A) larger than ion-ion forces.
B) about the same as all ion-ion forces.
C) much smaller than ion-ion forces.
D) between the force for °1 ions and °2 ions.
E) about a factor of two smaller the attraction of °1 ions.

F) C) and D)
G) All of the above

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The process of a solid converting directly to a gas is called


A) evaporation
B) condensation
C) deposition
D) sublimation
E) transformation

F) C) and D)
G) A) and B)

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In the phase diagram of water increasing pressure leads to lower melting temperatures.


A) this is true for all compounds
B) this is true for all polar compounds
C) this is true for all hydrogen bonding compounds
D) this is true for compounds with solid phases that are less dense than their liquid phases
E) this is true only for H2O, HF, and NH3

F) All of the above
G) C) and E)

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