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Which of the following atoms can expand its valence shell when bonding?


A) N
B) C
C) O
D) P
E) Al

F) A) and D)
G) A) and C)

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Which of the following has no net dipole moment?


A) N2O
B) NF3
C) H2Se
D) TeO3
E) CH3Cl

F) A) and D)
G) A) and C)

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In order for a noncyclic triatomic molecule to be bent, VSEPR theory requires that there must be two lone pairs on the central atom.

A) True
B) False

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In which one of the following structures does the central atom have a formal charge of +2?


A) In which one of the following structures does the central atom have a formal charge of +2? A)    B)    C)    D)    E)
B) In which one of the following structures does the central atom have a formal charge of +2? A)    B)    C)    D)    E)
C) In which one of the following structures does the central atom have a formal charge of +2? A)    B)    C)    D)    E)
D) In which one of the following structures does the central atom have a formal charge of +2? A)    B)    C)    D)    E)
E) In which one of the following structures does the central atom have a formal charge of +2? A)    B)    C)    D)    E)

F) A) and B)
G) A) and C)

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Which one of the following molecules does not have a dipole moment?


A) CS2
B) H2S
C) CH2Cl2
D) PH3
E) CH2O

F) B) and E)
G) A) and B)

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Select the Lewis structure in which formal charges are minimized for the periodate anion, IO4-.


A) Select the Lewis structure in which formal charges are minimized for the periodate anion, IO<sub>4</sub><sup>-</sup>. A)    B)    C)    D)    E)
B) Select the Lewis structure in which formal charges are minimized for the periodate anion, IO<sub>4</sub><sup>-</sup>. A)    B)    C)    D)    E)
C) Select the Lewis structure in which formal charges are minimized for the periodate anion, IO<sub>4</sub><sup>-</sup>. A)    B)    C)    D)    E)
D) Select the Lewis structure in which formal charges are minimized for the periodate anion, IO<sub>4</sub><sup>-</sup>. A)    B)    C)    D)    E)
E) Select the Lewis structure in which formal charges are minimized for the periodate anion, IO<sub>4</sub><sup>-</sup>. A)    B)    C)    D)    E)

F) B) and C)
G) D) and E)

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Boron never achieves an octet in any of its compounds.

A) True
B) False

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Which of the following elements would you expect most likely to be a central atom with an expanded valence shell?


A) Ne
B) P
C) N
D) C
E) B

F) B) and D)
G) C) and D)

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Which one of the following Lewis structures is definitely incorrect?


A) Which one of the following Lewis structures is definitely incorrect?  A)    B)    C)    D)    E)
B) Which one of the following Lewis structures is definitely incorrect?  A)    B)    C)    D)    E)
C) Which one of the following Lewis structures is definitely incorrect?  A)    B)    C)    D)    E)
D) Which one of the following Lewis structures is definitely incorrect?  A)    B)    C)    D)    E)
E) Which one of the following Lewis structures is definitely incorrect?  A)    B)    C)    D)    E)

F) None of the above
G) B) and D)

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A molecule that contains polar bonds will always have a dipole moment.

A) True
B) False

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What is the molecular shape of NO2- as predicted by the VSEPR theory?


A) linear
B) trigonal planar
C) bent
D) tetrahedral
E) resonant

F) B) and D)
G) A) and B)

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According to VSEPR theory, a molecule with the general formula AX4 will have a ______ molecular shape.


A) bent
B) trigonal planar
C) trigonal pyramidal
D) square planar
E) tetrahedral

F) C) and D)
G) B) and D)

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What is the molecular shape of BCl3 as predicted by the VSEPR theory?


A) linear
B) trigonal planar
C) bent
D) tetrahedral
E) trigonal pyramidal

F) All of the above
G) C) and D)

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Predict the actual bond angle in SeCl2 using the VSEPR theory.


A) more than 120°
B) between 109° and 120°
C) between 90° and 109°
D) exactly 90°
E) less than 90°

F) B) and C)
G) B) and D)

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C

What is the molecular shape of ClO3F as predicted by the VSEPR theory? What is the molecular shape of ClO<sub>3</sub>F as predicted by the VSEPR theory?   A)  trigonal pyramidal B)  square planar C)  square pyramidal D)  tetrahedral E)  octahedral


A) trigonal pyramidal
B) square planar
C) square pyramidal
D) tetrahedral
E) octahedral

F) B) and C)
G) C) and E)

Correct Answer

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Hydrazine, N2H4, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure.


A) Hydrazine, N<sub>2</sub>H<sub>4</sub>, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure. A)    B)    C)    D)    E)  None of these choices are correct.
B) Hydrazine, N<sub>2</sub>H<sub>4</sub>, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure. A)    B)    C)    D)    E)  None of these choices are correct.
C) Hydrazine, N<sub>2</sub>H<sub>4</sub>, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure. A)    B)    C)    D)    E)  None of these choices are correct.
D) Hydrazine, N<sub>2</sub>H<sub>4</sub>, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure. A)    B)    C)    D)    E)  None of these choices are correct.
E) None of these choices are correct.

F) B) and C)
G) None of the above

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C

Predict the ideal bond angles around carbon in C2I2 using the molecular shape given by the VSEPR theory.


A) 90°
B) 109°
C) 120°
D) 180°
E) None of these choices are correct.

F) None of the above
G) D) and E)

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What is the molecular shape of HOF as predicted by the VSEPR theory?


A) trigonal pyramidal
B) trigonal
C) tetrahedral
D) linear
E) bent

F) All of the above
G) B) and E)

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Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl2.


A) Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl<sub>2</sub>. A)    B)    C)    D)    E)  None of these choices are correct.
B) Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl<sub>2</sub>. A)    B)    C)    D)    E)  None of these choices are correct.
C) Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl<sub>2</sub>. A)    B)    C)    D)    E)  None of these choices are correct.
D) Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl<sub>2</sub>. A)    B)    C)    D)    E)  None of these choices are correct.
E) None of these choices are correct.

F) B) and E)
G) B) and D)

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B

According to VSEPR theory, a molecule with the general formula AX3E2 will have a _____ molecular shape.


A) trigonal pyramidal
B) trigonal bipyramidal
C) trigonal planar
D) T-shaped
E) see-saw

F) A) and D)
G) A) and B)

Correct Answer

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